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Citroxanthin

PubChem CID: 5281246

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Compound Synonyms Citroxanthin, Mutatochrome, 515-06-0, 5,8-Monoepoxy-beta-carotene, MO0US97U17, 4,4,7a-trimethyl-2-[(2E,4E,6E,8E,10E,12E,14E,16E)-6,11,15-trimethyl-17-(2,6,6-trimethylcyclohexen-1-yl)heptadeca-2,4,6,8,10,12,14,16-octaen-2-yl]-2,5,6,7-tetrahydro-1-benzofuran, MUTATOCHROME, ALL-TRANS-, 5,8-EPOXY-5,8-DIHYDRO-.BETA.,.BETA.-CAROTENE, .BETA.,.BETA.-CAROTENE, 5,8-EPOXY-5,8-DIHYDRO-, Flavacin, Flavacin?, 4,4,7a-trimethyl-2-((2E,4E,6E,8E,10E,12E,14E,16E)-6,11,15-trimethyl-17-(2,6,6-trimethylcyclohexen-1-yl)heptadeca-2,4,6,8,10,12,14,16-octaen-2-yl)-2,5,6,7-tetrahydro-1-benzofuran, beta-Carotene 5,8-epoxide, SCHEMBL39732, CHEBI:7037, LMPR01070277, 5,8-Epoxy-5,8-dihydro-b,b-carotene, C08605, 5,8-EPOXY-5,8-DIHYDRO-BETA,BETA-CAROTENE, BETA,BETA-CAROTENE, 5,8-EPOXY-5,8-DIHYDRO-, Q15425813, beta,beta-Carotene, 5,8-epoxy-5,8-dihydro-, (9cis)-
Ghose Rule False
Classyfire Kingdom Organic compounds
Topological Polar Surface Area 9.2
Hydrogen Bond Donor Count 0.0
Pfizer 3 75 Rule False
Scaffold Graph Level C(CCCCCCCCC1CC2CCCCC2C1)CCCCCCCC1CCCCC1
Np Classifier Class Carotenoids (C40, β-β)
Deep Smiles C/C=CC=CC=CC=CC=CCC=CCO5)C)CCCC6C)C)))))))))/C)))))/C))))))/C=C/C=C/C=C/C=CC)CCCC6C)C)))))))))C
Heavy Atom Count 41.0
Classyfire Class Prenol lipids
Description Mutatochrome, also known as citroxanthin, is a member of the class of compounds known as xanthophylls. Xanthophylls are carotenoids containing an oxygenated carotene backbone. Carotenes are characterized by the presence of two end-groups (mostly cyclohexene rings, but also cyclopentene rings or acyclic groups) linked by a long branched alkyl chain. Carotenes belonging form a subgroup of the carotenoids family. Xanthophylls arise by oxygenation of the carotene backbone. Thus, mutatochrome is considered to be an isoprenoid lipid molecule. Mutatochrome is practically insoluble (in water) and an extremely weak basic (essentially neutral) compound (based on its pKa). Mutatochrome can be found in a number of food items such as passion fruit, citrus, sweet orange, and pepper (c. frutescens), which makes mutatochrome a potential biomarker for the consumption of these food products. Mutatochrome (5,8-epoxy-β-carotene) is a carotenoid. It is the predominant carotenoid in the cap of the bolete mushroom Boletus luridus .
Scaffold Graph Node Level C(CCCCCCCCC1CC2CCCCC2O1)CCCCCCCC1CCCCC1
Classyfire Subclass Tetraterpenoids
Isotope Atom Count 0.0
Molecular Complexity 1260.0
Database Name fooddb_chem_all;hmdb_chem_all;imppat_phytochem;pubchem
Defined Atom Stereocenter Count 0.0
Iupac Name 4,4,7a-trimethyl-2-[(2E,4E,6E,8E,10E,12E,14E,16E)-6,11,15-trimethyl-17-(2,6,6-trimethylcyclohexen-1-yl)heptadeca-2,4,6,8,10,12,14,16-octaen-2-yl]-2,5,6,7-tetrahydro-1-benzofuran
Class Prenol lipids
Veber Rule True
Classyfire Superclass Lipids and lipid-like molecules
Xlogp 12.5
Superclass Lipids and lipid-like molecules
Subclass Tetraterpenoids
Gsk 4 400 Rule False
Molecular Formula C40H56O
Scaffold Graph Node Bond Level C(C=CC=CC=CC=CC1C=C2CCCCC2O1)=CC=CC=CC=CC1=CCCCC1
Inchi Key GFPJSSAOISEBQL-FZKBJVJCSA-N
Silicos It Class Moderately soluble
Rotatable Bond Count 9.0
State Solid
Synonyms 5,8-Epoxy-5,8-dihydro-b,b-carotene, 5,8-Monoepoxy-beta-carotene, beta-Carotene 5,8-epoxide, Flavacin?, Mutatochrome, mutatochrome, mutatochrome (5,8-epoxy-5,8-dihydro-β,β-carotene)
Esol Class Poorly soluble
Functional Groups CC(C)=C(C)/C=C/C(C)=C/C=C/C(C)=C/C=C/C=C(C)/C=C/C=C(/C)C, CC=C(C)C, COC
Compound Name Citroxanthin
Kingdom Organic compounds
Exact Mass 552.433
Formal Charge 0.0
Monoisotopic Mass 552.433
Hydrogen Bond Acceptor Count 1.0
Molecular Weight 552.9
Gi Absorption False
Covalent Unit Count 1.0
Total Atom Stereocenter Count 2.0
Total Bond Stereocenter Count 8.0
Molecular Framework Aliphatic heteropolycyclic compounds
Lipinski Rule Of 5 False
Inchi InChI=1S/C40H56O/c1-30(19-13-20-32(3)24-25-35-33(4)23-15-26-38(35,6)7)17-11-12-18-31(2)21-14-22-34(5)36-29-37-39(8,9)27-16-28-40(37,10)41-36/h11-14,17-22,24-25,29,36H,15-16,23,26-28H2,1-10H3/b12-11+,19-13+,21-14+,25-24+,30-17+,31-18+,32-20+,34-22+
Smiles CC1=C(C(CCC1)(C)C)/C=C/C(=C/C=C/C(=C/C=C/C=C(\C)/C=C/C=C(\C)/C2C=C3C(CCCC3(O2)C)(C)C)/C)/C
Np Classifier Biosynthetic Pathway Terpenoids
Defined Bond Stereocenter Count 8.0
Egan Rule False
Taxonomy Direct Parent Xanthophylls
Np Classifier Superclass Carotenoids (C40)

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