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2(R)-Hydroxy-2-methylbutyronitrile-beta-D-glucopyranoside

PubChem CID: 4626626

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Compound Synonyms 2(R)-Hydroxy-2-methylbutyronitrile-beta-D-glucopyranoside, 2-(beta-D-Glucopyranosyloxy)-2-methyl-(R)-Butanenitrile, AKOS030242404
Topological Polar Surface Area 123.0
Hydrogen Bond Donor Count 4.0
Inchi Key WEWBWVMTOYUPHH-UHFFFAOYSA-N
Rotatable Bond Count 4.0
State Solid
Synonyms 2(R)-Hydroxy-2-methylbutyronitrile-beta-D-glucopyranoside, Butanenitrile, 2-(beta-D-glucopyranosyloxy)-2-methyl-, (R)-, Lotaustralin, 2-(beta-D-Glucopyranosyloxy)-2-methyl-(R)-butanenitrile, 2(R)-Hydroxy-2-methylbutyronitrile-beta-D- glucopyranoside, Lotaustralin, (S)-isomer
Heavy Atom Count 18.0
Compound Name 2(R)-Hydroxy-2-methylbutyronitrile-beta-D-glucopyranoside
Kingdom Organic compounds
Description Glycoside from Trifolium repens (white clover) and other plants Lotaustralin is a cyanogenic glucoside found in small amounts in name giving Fabaceae Lotus australis, cassava (Manihot esculenta), lima bean (Phaseolus lunatus), roseroot (Rhodiola rosea) and white clover (Trifolium repens), among other plants. Lotaustralin is structurally related to linamarin, another glucoside found in these plants, and differs from it only by the presence of an extra methyl group. Both lotaustralin and linamarin may be hydrolysed by the enzyme linamarase to form glucose and a precursor to the toxic compound hydrogen cyanide.
Exact Mass 261.121
Formal Charge 0.0
Monoisotopic Mass 261.121
Isotope Atom Count 0.0
Molecular Complexity 329.0
Hydrogen Bond Acceptor Count 7.0
Molecular Weight 261.269
Database Name fooddb_chem_all;hmdb_chem_all;pubchem
Covalent Unit Count 1.0
Uniprot Id Q9H227
Defined Atom Stereocenter Count 0.0
Iupac Name 2-methyl-2-[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxybutanenitrile
Total Atom Stereocenter Count 6.0
Molecular Framework Aliphatic heteromonocyclic compounds
Total Bond Stereocenter Count 0.0
Class Organooxygen compounds
Inchi InChI=1S/C11H19NO6/c1-3-11(2,5-12)18-10-9(16)8(15)7(14)6(4-13)17-10/h6-10,13-16H,3-4H2,1-2H3
Smiles CCC(C)(C#N)OC1C(C(C(C(O1)CO)O)O)O
Xlogp -1.1
Superclass Organic oxygen compounds
Defined Bond Stereocenter Count 0.0
Subclass Carbohydrates and carbohydrate conjugates
Taxonomy Direct Parent Cyanogenic glycosides
Molecular Formula C11H19NO6

  • 1. Outgoing r'ship FOUND_IN to/from Linum Usitatissimum (Plant) Rel Props:Source_db:fooddb_chem_all