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Solamarin, beta

PubChem CID: 437080

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Compound Synonyms SOLAMARIN, BETA, .beta.-Solamarine, 2-[4-hydroxy-2-(hydroxymethyl)-6-(5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-piperidine]-16-yl)oxy-5-(3,4,5-trihydroxy-6-methyloxan-2-yl)oxyoxan-3-yl]oxy-6-methyloxane-3,4,5-triol, NSC94735, NSC407810, CHEMBL2005327, SCHEMBL25775453, BCP18605, Solamargin, (c)(1/2)-Solanigrine, LS-15468, BRD-A65562236-001-01-2, Spirosol-5-en-3-yl 2,4-bis-O-(6-deoxyhexopyranosyl)hexopyranoside, 2-[4-hydroxy-2-(hydroxymethyl)-6-(5'-tetramethylspiro[[?]-2,2'-piperidine]yl)oxy-5-(3,4,5-trihydroxy-6-methyl-tetrahydropyran-2-yl)oxy-tetrahydropyran-3-yl]oxy-6-methyl-tetrahydropyran-3,4,5-triol
Topological Polar Surface Area 238.0
Hydrogen Bond Donor Count 9.0
Heavy Atom Count 61.0
Description Solamargine, also known as beta-solamarine, is a member of the class of compounds known as steroidal saponins. Steroidal saponins are saponins in which the aglycone moiety is a steroid. The steroidal aglycone is usually a spirostane, furostane, spirosolane, solanidane, or curcubitacin derivative. Solamargine is practically insoluble (in water) and a very weakly acidic compound (based on its pKa). Solamargine can be found in eggplant, which makes solamargine a potential biomarker for the consumption of this food product. Solamargine is a poisonous chemical compound that occurs in plants of the Solanaceae family, such as potatoes, tomatoes, and eggplants. It has been also isolated from Solanum nigrum fungal endophyte Aspergillus flavus. It is a glycoalkaloid derived from the steroidal alkaloid solasodine .
Isotope Atom Count 0.0
Molecular Complexity 1610.0
Database Name fooddb_chem_all;hmdb_chem_all;pubchem
Defined Atom Stereocenter Count 0.0
Iupac Name 2-[4-hydroxy-2-(hydroxymethyl)-6-(5',7,9,13-tetramethylspiro[5-oxapentacyclo[10.8.0.02,9.04,8.013,18]icos-18-ene-6,2'-piperidine]-16-yl)oxy-5-(3,4,5-trihydroxy-6-methyloxan-2-yl)oxyoxan-3-yl]oxy-6-methyloxane-3,4,5-triol
Nih Violation True
Class Azaspirodecane derivatives
Xlogp 1.1
Superclass Organoheterocyclic compounds
Is Pains False
Molecular Formula C45H73NO15
Inchi Key MBWUSSKCCUMJHO-UHFFFAOYSA-N
Rotatable Bond Count 7.0
Synonyms Solamargine, beta-Solamarine, Solasonine, alpha-Solasonine, alpha-Solamarine, alpha-Solamarine, (3beta,22alpha,25R)-isomer
Compound Name Solamarin, beta
Kingdom Organic compounds
Exact Mass 867.498
Formal Charge 0.0
Brenk Violation True
Monoisotopic Mass 867.498
Hydrogen Bond Acceptor Count 16.0
Molecular Weight 868.1
Covalent Unit Count 1.0
Total Atom Stereocenter Count 26.0
Total Bond Stereocenter Count 0.0
Molecular Framework Aliphatic heteropolycyclic compounds
Inchi InChI=1S/C45H73NO15/c1-19-9-14-45(46-17-19)20(2)30-28(61-45)16-27-25-8-7-23-15-24(10-12-43(23,5)26(25)11-13-44(27,30)6)57-42-39(60-41-36(53)34(51)32(49)22(4)56-41)37(54)38(29(18-47)58-42)59-40-35(52)33(50)31(48)21(3)55-40/h7,19-22,24-42,46-54H,8-18H2,1-6H3
Smiles CC1CCC2(C(C3C(O2)CC4C3(CCC5C4CC=C6C5(CCC(C6)OC7C(C(C(C(O7)CO)OC8C(C(C(C(O8)C)O)O)O)O)OC9C(C(C(C(O9)C)O)O)O)C)C)C)NC1
Defined Bond Stereocenter Count 0.0
Taxonomy Direct Parent Azaspirodecane derivatives

  • 1. Outgoing r'ship FOUND_IN to/from Solanum Melongena (Plant) Rel Props:Source_db:fooddb_chem_all